Mudstones of the Tanqua Basin, South Africa: an analysis of lateral and stratigraphic variations within mudstones, and a comparison of mudstones within and between turbidite fans     

P. O. D. Andersson  R. H. Worden† 《Sedimentology》2004,51(3):479-502

Permian deep‐water mudstones in the Tanqua Basin, South Africa, have been studied using geochemical and spectral gamma ray techniques. The mudstones occur as thick sequences between sand‐rich submarine fans, but also occur as thinner mud‐rich units within each fan. The interfan mudstones are interpreted to have accumulated during transgression and the consequent period of relatively high sea‐level, while the submarine fans and their intrafan mudstones were deposited during regression and relatively low sea‐level. Geochemical analyses revealed systematic differences between interfan and intrafan mudstones because the two types of mudstones have slightly different source lithologies. Differences between the two types of mudstone suggest that changes in relative sea‐level played a role in controlling exposure of sediment source areas. There are geochemical signals that display systematic stratigraphic trends within both interfan and intrafan mudstones. These are best explained by gradual denudation, exposure and weathering of different lithologies within a single sediment source area. Both interfan and intrafan mudstones have uniform geochemical signals along the flow direction except for the relative amount of uranium. It is most likely that the basinward increase in uranium in the mudstones is the result of reduced clastic dilution of uranium‐bearing pelagic fallout.  相似文献   

The use of heavy metal concentrations and dendrochronology in the reconstruction of sediment accumulation, Ma a Panew River Valley, southern Poland     

Dariusz Ciszewski  Ireneusz Malik 《Geomorphology》2004,58(1-4):161-174

Heavy metal concentrations were investigated in overbank sediments of the Mala Panew River, southern Poland. Samples were collected from seven vertical profiles located within channel infills of a 20th century floodplain at three sites, each up to 50 m wide. In each profile, 15–24 samples were collected and analysed for Ba, Cd, Cu, Pb, and Zn. Sequential extraction of these elements was carried out in the 0.063-mm fraction of selected samples. Additionally, the age of the oldest trees growing close to the profiles has been used to estimate the initiation of sediment accumulation there. Ba, Cu, and Pb, which occur mostly in less mobile, moderately reducible, and residual fractions, were used for sediment dating. Zn and Cd, which in 50–75% occur in the mobile exchangeable fraction, were not suitable for dating. Correlation of Ba, Cu, and Pb concentrations in vertical profiles with changes in the load of effluents discharged to the river showed abrupt changes in the thickness of the strongly polluted sediments across the floodplains. A comparison of the relative changes between heavy metal peaks in sediments of similar age in the different profiles suggests a variable rate of downward metal migration. In general, none of the heavy metals investigated seems to have been mobilised within the stratigraphic layers above the water table. In layers located at stratigraphically lower levels, the Zn and Cd peaks seem to migrate several centimetres to several decimetres down in the profile. In profiles inundated for several weeks every year, Zn and Cd, as well as the relatively less mobile Ba, Cu, and Pb, have migrated downward by several decimetres. The investigation shows that frequent fluctuations of the water table have blurred the original depositional metal patterns of metal concentrations within a period of less than 40 years.  相似文献   

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments     

Edeltrauda Helios Rybicka  Ewa Adamiec  Urszula Aleksander-Kwaterczak 《Limnologica》2005,35(3):185-198

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.  相似文献   

Sorption of Eu~(3+) onto nano-size silica-water interfaces     

HU Ping    YIN Xiulan  ZHAO Linghu & LI Dien . Department of Earth Sciences  China University of Geosciences  Wuhan  China  . Northeastern Illinois University  Chicago  IL  USA  . China Institute of Geo-Environmental Monitoring  Beijing  China  . Division of Chemistry  Los Alamos National Laboratory  Los Alamos  NM  USA 《中国科学D辑(英文版)》2005,48(11)

A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta…  相似文献   

Temperature and pH Dependence of Some Metals Leaching from Fly Ash of Municipal Solid Waste     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Takeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2005,55(4):357-372

Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws.  相似文献   

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China   总被引：7，自引：0，他引：7  

Xue Song WANG  Yong QIN 《Environmental Geology》2005,49(1):10-18

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study     

Brijraj K. Das 《Environmental Geology》2005,49(2):230-239

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.  相似文献   

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania     

R. M. Florea  A. I. Stoica  G. E. Baiulescu  P. Capotă 《Environmental Geology》2005,48(8):1132-1136

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.  相似文献   

Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh   总被引：1，自引：0，他引：1  

Faruque Ahmed  M. Hawa Bibi  M. Hussain Monsur  Hiroaki Ishiga 《Environmental Geology》2005,48(1):25-36

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.  相似文献   

Chemical effects of a near-to-nature detention pond on a small urban headwater     

《Limnologica》2017

The near-to-nature approach has been established as best practice for stormwater management. However, pollutant mobility within such systems and its impact on small receiving waters are partly unexplained. The study takes place in an urbanised headwater catchment in south-western Germany with an area of 0.4 km². Runoff from roofs, roads, parking lots and gardens is collected in wells or trenches and stored in private and public dry detention basins. Accordingly, this study investigates pollutant input to a detention pond, removal efficiency and the associated effects on the receiving water.Grab samples with high temporal resolution of the receiving water (16 flood events with 315 samples and 41 baseflow samples), the three inflows of the detention basin and its outflow (four flood events with 64 samples) were taken. The outflow of the dry pond is recovered in the hydro- and chemographs of the receiving water. Runoff from roads with increased traffic volume caused the highest PAH inputs and runoff from the residential area showed the highest zinc concentrations, which partly infringe European Environmental Quality Standards. Yearly pollutant inputs (DOC, TSS, PAH, nutrients, metals) from the settlement into the tributary are reduced in the detention pond by up to 80%.  相似文献